Nolas G, Slack G, Morelli D, Tritt T, Ehrlich A (1996) The effect of rare earth filling on the lattice thermal conductivity of skutterudites. J Appl Phys 112:083718Įilertsen J, Rouvimov S, Subramanian M (2012) Rattler-seeded InSb nanoinclusions from metastable indium-filled InCoSb skutterudites for high-performance thermoelectrics. Crystallogr Rep 52:28–36ĭong Y, Puneet P, Tritt T, Martin J, Nolas G (2012) High temperature thermoelectric properties of p-type skutterudites Ba xYb 圜o 4-zFe zSb 12. RSC Adv 5:41653Īleksandrov KS, Beznosikov BV (2007) Crystal chemistry and prediction of compounds with a structure of skutterudite type. Rull-Bravo M, Moure A, Fernandez JF, Martin-Gonzalez M (2015) Skutterudites as thermoelectric materials: revisited. In: Proceedings of the XVI international conference on thermoelectrics, 26–29 August 1997 Phys Rev B 56:7376–7383įleurial J, Caillat T, Borshchevsky A (1997) Skutterudites: an update.
Morelli D, Meisner G, Chen B, Hu S, Uher C (1997) Cerium filling and doping of cobalt triantimonide. Lyons A, Gruska R, Case C, Subbarao S, Wold A (1978) The preparation and characterization of some skutterudite related compounds. Annu Rev Mater Sci 29:89–116Īckermann J, Wold A (1977) The preparation and characterization of the cobalt skutterudites CoP 3, CoSb 3, CoAs 3. Nolas G, Morelli D, Tritt T (1999) Skutterudites: a phonon-glass-electron crystal approach to advanced thermoelectric energy conversion applications. Sherman B, Heikes R, Ure R (1960) Calculation of efficiency of thermoelectric devices. Due to the low Seebeck coefficients, the alloys exhibited low figure of merits (ZT) <0.05. The combination of transmission electron microscopy with electron energy loss spectroscopy and powder X-ray diffraction established that Sn can substitute on 2a and 24g sites in the skutterudite structure. Seebeck coefficients were low, ranging from −40 to 58 µV K −1. N-type and p-type skutterudite samples with the composition Co xNi 4− xSb 12− ySn y were synthesized with composition range 0 0.8 and negative otherwise.
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